
Intelligent Polymers Research Lab
Electrochemical Sensing
A sensor serves as a crucial device that can detect and react to various stimuli, encompassing factors like temperature, light, sound, pressure, concentration, or movement. It accomplishes this by converting the observed stimulus into an electrical impulse, enabling us to measure alterations in an intrinsic property of the material it's constructed from. Among the various sensor types, conductive polymer sensors stand out due to several compelling advantages. These include their remarkable sensitivity, rapid response time, ease of production, capacity for operation at room temperature, and the flexibility to adjust both their chemical and physical attributes by incorporating different substituents.
Conducting polymers represent some of the simplest systems capable of sensing or responding to internal or external perturbations, whether they be chemical, electrical, thermal, or otherwise. In essence, they function as multi-step macromolecular motors, capable of transitioning through n consecutive chemical equilibrium stages or n consecutive fundamental conformational energetic states in a progressive and reversible manner, all under precise electrochemical control. In this intricate dance of molecular-level changes, the sensor's output is determined by several key parameters, including the reaction rate, electrode potential, and the energy associated with the reaction (or the energy consumed). These magnitudes are essential for gauging and understanding the sensor's response to the environment.